Poly[ethylenediammonium [tris[μ3-hydrogenphosphato(2−)]dicadmium] monohydrate]
نویسندگان
چکیده
The title compound, {(C(2)H(10)N(2))[Cd(2)(HPO(4))(3)]·H(2)O}(n), was synthesized under hydro-thermal conditions. The structure of this hybrid compound consists of CdO(6), CdO(5) and PO(4) polyhedra arranged so as to build an anionic inorganic layer, namely [Cd(2)(HPO(4))(3)](2-), parallel to the ab plane. The edge-sharing CdO(6) octa-hedra form infinite chains running along the a axis and are linked by CdO(5) and PO(4) polyhedra. The ethyl-ene-diammonium cation and the water mol-ecule are located between two adjacent inorganic layers and ensure the cohesion of the structure via N-H⋯O and O-H⋯O hydrogen bonds.
منابع مشابه
A one-dimensional inorganic–organic hybrid compound: catena-poly[ethylenediammonium [indate(III)-di-μ-hydrogenphosphato(V)-μ-hydroxido] monohydrate]
The title compound, (C(2)H(10)N(2))[In(HPO(4))(2)(OH)]·H(2)O, was synthesized under hydro-thermal conditions. The structure of this hybrid compound consists of isolated inorganic chains with composition (∞)[In(HPO(4))(4/2)(OH)(2/2)] running along [010]. The coordination of the In(III) atom is distorted octa-hedral. The ethyl-enediammonium cation and the disordered water mol-ecule (site-occupati...
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